For elements such as Pb, Zn, and Cu, which are the major contaminants in the study area, the validation of the method gave good results, revealing the convergence of results for most sampling points. Finally, our study showed that the results obtained by SEM-EDX analysis can be comparable to quantitative results (ICP-MS analysis).A method quantifying 16 polycyclic aromatic hydrocarbons (PAHs) in wood vinegars (WVs) obtained from slow pyrolysis of biomass with ultrasonic-assisted liquid-liquid extraction/gas chromatography-mass spectrometry (USALLE/GC-MS) was established. The recovery range was 83-128%, and the relative standard deviations (RSD%) were less than 15% except naphthalene, acenaphthylene and acenaphthene. Acenaphthylene, acenaphthene, fluorene, anthracene, phenanthrene, fluoranthene, and pyrene were observed in all samples and the other 9 compounds, including benzopyrene (B[a]P), were not detected. The concentration of ?PAHs referred to the sum total of 7 PAHs mentioned above was 22.0-498.3 μg L-1. The PAHs concentration increased with the increasing pyrolysis temperature in bamboo willow WV, pinus sylvestris WV, and corncob WV, while it increased initially, and then decreased with a maximum at 550 °C in rice husk WV. The ?PAHs concentration increased with a higher heating rate in the white pine WV, while rice husk WV and cornstalk WV showed the opposite trend. The varied condensed aromatic ring number showed that 3-ring PAHs relatively were the main component in all kind WVs. 3-ring PAHs increased with increasing temperatures, while 4-ring PAHs showed an opposite trend in sawdust WV and corncob WVs. A higher cellulose content in sawdust enhanced the reaction of lignin leading to a higher concentration of PAHs than that in straws and leaves. Calculations of the toxicity equivalents of PAHs in WVs indicated that anthracene was the most toxic among the PAHs, and the pinus sylvestris WV had the highest risk of ?PAHs toxicity in all WVs.Anaerobic digestion is widely used for the treatment of wastewater for its low costs and bioenergy production, but the performances of anaerobic digestion often need improving in practical applications. The addition of conductive materials could lead to direct interspecies electron transfer (DIET) among the anaerobic microorganisms, and consequently enhance the efficiencies of anaerobic digestion. In this paper, the effects of DIET via conductive materials on chemical organic demand (COD) removal, volatile fatty acid (VFA) consumption and methane production were reviewed. https://www.selleckchem.com/products/Aminocaproic-acid(Amicar).html The reports on the increase of conductive microorganisms due to the addition of conductive materials were discussed. Results regarding activities of microorganisms and morphology and properties of sludge were described and commented, and future research needs were also proposed which included better understanding of the roles of DIET in each step of anaerobic digestion, mechanisms of metabolism of pollutants in DIET-established systems and inhibition of excessive dosage of conductive materials.The need for a more sustainable wastewater treatment is more relevant now due to climate change. Production and reuse of methane from anaerobic treatment is one pathway. However, this is defeated by the presence of dissolved methane in the effluent and would be released to the environment, adding to the greenhouse gas emissions. This review paper provided summary and analysis of studies involved in the production of dissolved methane from AnMBR, focusing with actual methane measurement (gas and dissolved) from AnMBR with different types of wastewater. Then more focused discussion and analysis on the use of membrane-based technology or membrane contactors in the recovery of dissolved methane from AnMBR effluent are included, with its development and energy analysis. The dissolved methane removal and recovery rate of membrane contactors can be as high as 96% and 0.05 mol methane/m2/h, respectively, with very low additional energy requirement of 0.01 kWh/m3 for the recovery. Future perspectives presented focus on the long-term evaluation and modelling of membrane contactors and on the membrane modifications to improve the selectivity of membranes to methane and to limit their fouling and wetting, thus making the technology more economical for resource recovery.Arsenic is frequently found in poultry waste, most of which is transformed from feed additive organoarsenicals, resulting in arsenic pollution of soils and water around poultry farms. The North China Plain, an important area for livestock breeding of China, was chosen to investigate the pollution characteristics and assess the health risk of arsenic around chicken farms. Among the 138 chicken farms sampled, almost no roxarsone, a common organoarsenical, was detected in chicken feeds, manure, and surface soils, while the detectable rate of other arsenic species was high. Because of long-term enrichment, the concentrations of arsenic species in manure were generally higher than that in feed. As(III) was the main inorganic arsenic species in the manure, where is reducing environment. In surface soils beneath the accumulated manure, As(V) was the predominant arsenic species with 100% detectable rate. The detectable rate and average concentrations at 0 cm were generally higher than those at 25 cm depth, indicating that arsenic accumulated in the surface soils. In addition, a typical conceptual diagram of arsenic was developed to clarify the pollution process from feed to soil. Through health risk assessment of inorganic arsenic, the carcinogenic risk (CR) and non-carcinogenic risk (non-CR) were both negligible. The city of Jiaozuo had the highest CR and non-CR, which was 11 times higher than that of the city with the lowest risks. This study presents a clear picture and evaluation of arsenic pollution on chicken farms, inspiring future studies assessing arsenic pollution after the ban of organoarsenicals.The migration of rare earth elements (REEs) has a major influence on the environment. However, little is known about REEs migration control by Dicranopteris dichotoma at REEs mines. Therefore, this study examined the horizontal and vertical migration of REEs using artificial rainfall and naive soil column experiments, respectively, and the REEs migration control of Dicranopteris dichotoma at REEs mines in south China. The REEs contents in the runoff and sediment were found to be 32.42 μg and 3.39 mg, respectively, in the artificial rainfall experiment. The mean REEs content and amount in the leaching liquor were 0.23 μg L-1 and 7.75 μg, respectively. The REEs content after leaching was significantly lower than that before leaching in the 0-5 cm layer, was significantly higher than that before leaching in the 5-10 cm layer. However, the REEs content of the Fe-Mn oxide form showed significant variation among the sites with different Dicranopteris dichotoma covers. Moreover, the runoff reducing rate rose with increasing Dicranopteris dichotoma cover, and the sediment reducing rate increased to the relatively stable stage when Dicranopteris dichotoma cover was equal or greater than 70%.